eChapters

10.1. Classification of Primates

The classification of primates is a complex topic that has been revised over time as our understanding of these fascinating creatures has evolved. Here’s a breakdown of the current classification system:

10.1.1. Order: Primates

Primates are an order of mammals that includes lemurs, lorises, tarsiers, monkeys, apes, and humans. They are characterized by a number of shared features, including:

• Opposable thumbs: This allows primates to grasp objects and manipulate their environment.

• Forward-facing eyes: This provides primates with depth perception, which is important for arboreal locomotion and foraging.

• Enlarged brains: Primates have relatively large brains for their body size, which is associated with their intelligence and complex social behaviors.

• Reduced sense of smell:Compared to other mammals, primates have a weaker sense of smell. This is thought to be due to their reliance on vision for foraging and social interaction.

3.1. Introduction

Various procedures performed on reptiles often necessitate chemical restraint or general anesthesia. Even routine tasks like physical examination and transportation can pose challenges, particularly with large or uncooperative reptilian patients. For safety reasons, venomous species are typically evaluated under chemical restraint. The respiratory anatomy and physiology of reptiles differ significantly from those of more familiar mammals, influencing their response to commonly used anesthetic agents. Historically, anesthetics recommended for reptiles had notable metabolic effects, but inhalant anesthesia has become more popular in recent times. Nonetheless, in species capable of anaerobic metabolism, induction with these agents may not be feasible (Girling 2013).

Rodents and lagomorphs are two distinct groups of mammals, often mistaken for each other due to some shared physical characteristics. However, they belong to different taxonomic orders and possess several key differences

5.1. Rodents

They belong to the order Rodentia and the example species include rats, mice, squirrels, hamsters, guinea pigs, beavers, and porcupines. Order Rodentia is the largest and most diversified mammalian group, differing widely in size, behavior, feeding habits, anatomy, and physiology. Based on the anatomy and functional differences of masseter muscles, it is divided into 3 suborders viz., Caviomorpha, Myomorpha, and Sciuromorpha. Caviomorpha is also called hystrichomorpha and includes guinea pigs, chinchillas and degu. The suborder Myomorpha includes mice, rats, hamsters and gerbils. These animals have the strongest ability to gnaw among animals in all 3 suborders. Sciuridae is a family that includes small or medium size rodents. This family consists of tree squirrels, ground or medium size squirrels, and large size squirrels also known as marmots or prairie dogs (Cynomys ludovicianus). Smaller and less bushy tailed squirrels are known as chipmunks (Tamias striatus) and flying squirrels (Glaucomys volans).

8.1. Classification

The ruminants belong to the Order Artiodactyla. The families in order of Artiodactyla include Camelidae, Tragulidae, Cervidae, Giraffidae, Antliocapridae, and Bovidae.

The family Camelidae includesGuanaco (Lama guanicoe), Llama (Lama glama), Alpaca or South American camelid mammal (Lama pacos), Dromedary camel (Camelus dromedarius), and Bactrian or two-humped camels (Camelus bactrianus).

The family Tragulidae includes Chevrotains originate from Africa (Hyumo schusaquaticus) and Chevrotains that originate from Asia (Tragulus species).

The family CervidaeincludesWhite tailed deer(Odococlius virginianus), Follow deer (Dama dama), Roe-deer (Capreolus capreolus), Axis deer (Axis axis), Reindeer (Rangiter tarandus), Musk deer (Moschus species) and Chinese water deer (Hydropotes species).

1.1. Introduction

Wildlife management often requires interventions to safely handle and transport animals. Chemical restraint, also known as immobilization or tranquilization, is a technique widely used to facilitate these processes (Hernandez, 2014). It involves the administration of drugs to temporarily immobilize wild animals, allowing for various procedures such as veterinary medical examinations, tagging, relocation, or rehabilitation. This chapter provides an overview of the principles, methods, drugs, and considerations involved in the chemical restraint of wild animals.

It has been often stated that the most important techniques required by the zoo veterinarian are those used in the capture and restraint of the patient. These techniques have developed into a highly technical science (Clarke et al., 2014). In the early days of zoos, the only practical method was to manually catch and hold the patient. Modern techniques, however, permit a veterinarian to shoot a CO2 powered gun, which discharges a projectile syringe at an animal resulting in complete immobilization of the animal (Jacques et al., 2009). This is accomplished without any physical contact between the patient and his captors.

The constitution of different solutions plays a significant role in successful demonstration of anatomical techniques especially the special stains. The sincerety begins at the time of fixation of the tissues and deviation at any step may lead to failure of procedure. The chemical reagents required for a particular method have been enlisted at their sites however; the commonly used chemicals are comprehended at one place for convenience of the users.

Synthesis of Zn Oxide Nanoparticle

Aim

To synthesize Zn oxide nanoparticle

Introduction

Zinc oxide nanoparticle are effective anti-bacterial and antiodur agent. They can be synthesized by number of techniques including hydrothermal methods. Their synthesis using solvothermal process is described, (Aneesh et al., 2007).

Chemical Synthesis Methods

Several methods can be used for the production of these nanoparticles, namely: (i) top-down methods (Li et al., 2006) such as vacuum sputtering (Kuhn et al., 2002) or the decomposition of iron penta carbonyl (Fe(CO)5) in organic solvents (Karlsson et al., 2005); and (ii) bottom-up methods that promote the ‘growth’ of the nanostructures via chemical synthesis, for example through the reaction of iron(II) or iron(III) salts with sodium borohydride (Wang and Zhang, 1997). However, these methods present several limitations and problems; the top-down methods are generally expensive and require specific and costly equipment while the drawbacks of the bottom-up approaches are related to safety issues due to the toxicity of sodium borohydride, the production of flammable hydrogen gas during the process (Li et al., 2006), and the tendency to form large agglomerates, very fast and at a high extent, and therefore have a reduced reactivity and degradation efficiency.

Laboratory Tests

Sampling procedures

Samples from number of containers- As soon as the cans are received at the reception dock, remove the lid, mix contents of each can with a plunger and draw equal quantities from each container and mix together. Draw approximately 80 – 100 ml of sample for testing. If the cans are of same diameter, Alternatively, milk from different containers are first poured into a vat and then the sample is drawn by thorough mixing as above..

Samples from storage tank – Before drawing sample from storage tank, switch on the mechanical agitator and allow the contents to mix for 15-20 minutes. Discard first 1.0 L of milk. Transfer 250-500 ml of the mixed milk from the outlet valve into a sample bottle.

Samples from rail / road tankers- Open the lid of the tanker and insert a big plunger through the main hole and move it forward, downward and backward bring the plunger to the surface at each stroke. Continue mixing for 15-20 minutes. Draw proportionate quantities of sample with the help of suitable dipper from different levels. Draw 250-500 ml of well-mixed sample into the sample bottle. The total volume of individual composite sample should not be less than 150 ml.

Introduction

The compounds produced one kind of microbe that are poisonous to another type of microbes are known as antibiotics. Actinomycetous bacteria and certain fungi are the primary producers of antibiotics. Antibiotics have highly complicated chemical makeups and formulations, which are frequently unknown. To combat plant diseases, however, antibiotics were first introduced in 1950. Typically, plants absorb and then move systemically internal antibiotics used for managing plant diseases. Usually, they operate on the host or the pathogen directly or after going through transformation to control plant diseases. In addition to acting as eradicators, they also serve as protectors and offer resistance to the invasion of viruses, and their impact lasts for a while.

Introduction

• Nematicides are chemically synthesized products that kill or adversely affect nematodes.

• These products can have a nematicidal or nemastatic effect on nematodes.

• Nematicidal compounds are highly toxic and kill exposed nematodes.

• Nemastatic compounds do not kill nematodes but interfere with the migration of nematodes towards the roots of the host plant or delay nematode hatching.

• Many nematicides are broad spectrum, volatile, soil fumigant.

• They are not only active against nematodes, but also insects, fungi, bacteria, weed seeds and almost everything else that lives on the ground.

Key facts

    
•    The use of chemicals has many benefits, however, there are potential risks that some of these chemicals may cause harm to organisms and human health if they enter into the environment.
    
•    Harmful chemicals are those chemicals which are persistent, bio-accumulative, as well as toxic (PBT). 
    
•    Environmental or ecological risk assessment (ERA) consists of hazard identification, effect assessment, exposure assessment, risk characterization, risk classification, risk-benefit analysis, risk reduction and monitoring.
    
•    The five types of environmental monitoring are: chemical monitoring, bio-accumulation monitoring, biological effect monitoring, health monitoring and ecosystem monitoring. 
    
•    An integrated monitoring program is a coordinated monitoring activity comprising of both chemical and biological measurements in a variety of environmental compartments. There are four different monitoring levels in an integrated ERA, these are: suborganismals (biomarkers), organisms (bioassays), populations (bio-indicators) and ecosystems (ecological indicators).

Fruit drop just before harvest is a serious problem for various crop varieties. The severity of fruit drop is influenced by several factors but plant stress and premature ethylene production is at the basis of true physiological drop. Stress factors such as late season heat, primary and secondary pest infestation, and nutrient imbalance or deficiency, and heavy summer pruning, all can contribute to drop.

The use of flower inducers stimulates flower growth during the resting year so the tree produces annually. Flower inducers can also increase the number of viable blooms during the natural fruit producing year, for an increase in production. These can also be used on varieties that provide a crop every year, to boost harvest.

Abstract

Eight species including 1 variety, 2 macro and 6 micro-lichens from Garhwal Himalaya, c 1500-2700 m, have been found to glow and emit fluorescent light, when exposed to long wave-length (254 nm) ultra-violet radiataions. Taxonomy and chemistry of all these species have been critically evaluated. The recorded taxa belong to families Physciaceae (4 species); Pertusariaceae, Rhizocarpaceae (1 species each) and Lichen imperfecti (2 species). The reported taxa are: Buellia hemispherica Singh and Awasthi, B. sub-glaziouana Singh and Awasthi; Pertusaria pertusa (Weig.) Tuck., Pyxine berteriana (Fee) Imsh. var. himalayensis Awasthi; P. cocoes (Swartz) Nyl., Rhizocarpon geographicum (L.) DC.; Lepraria taxonomic species I and II.

Understanding the chemistry of submerged soil in the field of Geology, Pedology, Agriculture and other allied sectors draws attention to the research on characteristic changes in soil under submergence. It has been reported that, about 72% of the earth’s surface is covered by submerged soils or sediments . Rice plants have unique adaptation capability to grow under submerged soil and in any type of soil (acid/alkaline) condition or land situation (upland/lowland). The knowledge on changes of important physical, chemical and biological properties under submergence have important role to play in understanding the mechanisms of availability of nutrients to the plants and sustainability of the crop during its growing period.

9.0 Submerged Soil

The soils which are saturated with water for a longer period of time in a year to make the soil a distinctive gley horizons resulting from oxidation-reduction processes are called submerged soil. About 72% of the earth’s surface is covered with soil –submergence or sediments.

Soil  is an interface of inorganic and organic componentsof the planet earth, which combines carbon and nitrogen from the atmosphere with different mineral elements of the lithosphere through millions of microorganisms, intercepting energy from the sun and moisture from the hydrosphere and atmosphere. It is a source as well as sink to adsorb, desorb, fix or release mineral elements and gases, decompose organic residues, simultaneously and support the growth of plants. All these natural processes are accompanied by runoff, percolation and evapotranspiration processes of the hydrologic cycle. Thus, soil is a dynamic body that acquires properties in accordance with the forces, which act upon it. Many soil properties emanate from physical, chemical and biologically mediated reactions, where the factors like climate, vegetation, topography and time  influences the processes. Soil reaction is one of the most important chemical characteristics of the soil solution,which has both direct and indirect effects on plant nutrition.

11.1. What is acid soil?

Acid soils refer to those soils that are characterized with the presence of higher concentration of H⁺ in soil solution and at exchangeable sites or characterized with its high proton donating capacity such as aluminium (Al³⁺) on hydrolysis gives rise to proton. Both H⁺ and Al³⁺ are responsible to contribute soil acidity. Al³⁺ causes soil acidity indirectly by generating H⁺ through its hydrolysis, while H⁺ contributes directly. Therefore, due to more abundance of H⁺, they exhibit low soil pH and low base saturation (Ca²⁺, Mg²⁺, Na⁺ and K⁺). Such soil is considered as problematic soil because plant growth is affected adversely under acidic conditions and they suffer root injuries when grown in acid soils. Besides, soil acidity interferes in the soil nutrients availability to plants, making them either deficient to plants (such as phosphorus, calcium, magnesium, molybdenum) or toxic to plants for their more availability. Under acidic condition, Al, Mn and Fe are found in more soluble form. Thus, they are taken up by the plant in such a higher level that they become toxic to plants. Phosphorus becomes immobile due to the formation of insoluble compounds with aluminium and iron under acidic conditions. Ca, Mg and Mo also become unavailable in acid soil and show their deficiency symptoms. Soil acidity also affects soil microbial growth and thus, in turn, affects the nutrient dynamics in soil. Soil acidification is induced heavily under intensive agricultural practices such as increasing leaching due to more irrigation practices, addition of fertilizers, build-up of soil organic matter and many other possible ways.

Carbohydrates are the most abundant class of organic compounds found in living organisms. Carbohydrates are also called sugars and are found in plants and animals. Plants synthesize them through photosynthesis (endothermic) by fixing carbon, hydrogen, and oxygen in the presence of solar energy and chlorophyll pigments.
nCO2 + nH2O + energy → CnH2nOn + nO2
Carbohydrates are stored as starch in plants as a source of energy. They are also stored in animals as glycogen in muscles and the liver. They are also found in skeletal structures of cell walls in plants (cellulose), bacteria (peptidoglycans), insects, and crustaceans. This stored food is consumed by animals and man, and upon their oxidation in the body, energy is released for various metabolic activities (work, growth, and various productive functions). Compositionwise, plants are more prosperous in carbohydrates (30%) than animals (1%), with water at 60% and ash at 4%. Plants are poor in proteins (5%) and lipids (1%) as compared to proteins (20%) and lipids (15%) in animals.
2.1 Introduction to Carbohydrates
Carbohydrates or saccharides (sakcharon=sugar or sweetness) are a chemical term applied to a large group of substances, which are organic compounds containing elements Carbon, Hydrogen, and Oxygen in a ratio of 1:2:1. Hydrogen and Oxygen atoms are in the ratio of two to one as in water molecules. As the ratio of hydrogen to oxygen is like H2O, they are also known as “hydrates of carbon” and are represented as (CH2O)n. But there is an exception to this general formula. Deoxyribose (C5H1OO4) and rhamnose (C6H12O5) do not have the required ratio of 2:1 for hydrogen to oxygen. On the other side, some compounds possess this required ratio but are not carbohydrates, e.g., formaldehyde (CH2O), acetic acid (C2H4O2), and lactic acid (C3H6O3). Further, some carbohydrates have nitrogen(glucosamine), phosphorus, and sulfur but do not satisfy the above general formula. The simplest sugars are called monosugars or monosaccharides. There are two main functional groups in

Cheese is made from milk, with the addition of cream, buttermilk, and/or whey. This basic raw material is also called cheese milk. Cheese consists mainly of casein (the major protein of milk), other milk proteins, fat, other milk components, and a certain percentage of water, which is bound. Proteins are precipitated by enzymes and/or acidification as well as heat and are separated by suitable processes from the aqueous phase. (whey, serum). Cheese is most often molded, pressed, and salted and has fungal and bacterial culture additions. colorants, herbs, spices, and other non-dairy ingredients are also added to the cheese. It is consumed either fresh or at different stages of ripening.

Worldwide, there are more than 2000 types of cheese, sometimes made by very different manufacturing processes. A classification can be based on several aspects and is done in different countries according to different criteria. A general classification can be made for three major groups:

a. Rennet or natural cheese: manufactured straight from milk by using proteolytic enzymes (rennet) and acid, with a more or less pronounced ripening process.

b. Fresh cheese or non-ripened Cheese: Quarg, fresh cheese, and white cheese are examples. Its manufacturing process is similar to that of rennet cheese manufacturing, but it has a high degree of acidity and is not subjected to a proteolytic ripening process.

c. Long-life cheese (processed cheese): it is more often made from rennet cheese and is textured by thermal treatment and made shelf-stable.

Concentrated milk products are obtained through partial removal of water which increases the dry matter content of milk. The increase in dry matter content in concentrated milk is proportional to the degree of concentration. The milk concentrate may be prepared from either full-cream whole milk or fat-free skim milk.

Depending on the nature of raw material and other non-milk additives concentrated milks are classified into four broad categories.

1. Sweetened condensed milk

2. Evaporated milk or unsweetened condensed milk

3. Sterile milk concentrate

4. Reconstituted concentrated milk

Sweetened Condensed Milk

One of the earliest dairy products to be produced industrially is sweetened condensed milk. According to FSSA (2006), sweetened condensed milk is the product obtained by partial removal of water from the milk of cow/buffalo with the addition of sugar or a combination of sucrose with other sugars or by any other process that leads to a product of the same composition and characteristics. The fat and/or protein content of the milk may be adjusted by the addition and/or withdrawal of milk constituents in such a way as not to alter the whey protein to casein ratio of the milk being adjusted. It shall have a pleasant taste and flavor and be free from off-flavor and rancidity. It shall be free from any substance foreign to milk. It may contain food additives. It shall conform to the microbiological requirement as laid down by FSSA. The said product shall also conform to the following requirements

1.1 Introduction
Concentrated milks, like evaporated milk and sweetened condensed milk, serve as practical substitutes for fresh milk in regions where access to it is limited or where transportation and storage are challenging. These products go through specific processing techniques to reduce their water content, thereby improving their shelf life and transportability. Evaporated milk is created by removing water through evaporation and then
sterilizing it to prevent microbial growth. This process results in a thicker consistency and a slightly caramelized flavor due to the heat treatment. On the other hand, sweetened condensed milk is made by adding a significant amount of sucrose to the milk and excluding oxygen, which inhibits microbial growth. This results in a thick, sweet product suitable for various culinary uses. These concentrated milk products are usually packaged in small cans, making them convenient for storage and transportation. However, they are sometimes diluted before consumption with water to resemble the taste and consistency of fresh milk. In regions where even concentrated milks are not easily accessible, alternatives like whole milk powder or recombined milk are used. These alternatives involve dehydrating milk into powder form or reconstituting milk components to create a liquid similar to fresh milk. Innovations in processing and packaging have led to the development of alternative uses for concentrated milks, expanding their versatility beyond traditional applications. These products continue to provide essential dairy
nutrition in areas where fresh milk is scarce or hard to obtain, offering a shelfstable solution to meet dietary needs.

Chemistry of Creaming

After being drawn from animals, normal milk will form a cream layer on standing. Because of the difference in density between fat globules (920 kg m−3 at room temperature) and milk plasma (density 1030 kg m−3), the granules tend to rise. This causes creaming, which we often want to prevent and it enables milk to be separated into cream and skim milk. Creaming is much enhanced when the globules have been aggregated into flocculates, clusters, or granules.

Cream Ripening

This unit operation serves as an intensive preparation of the cream for the churning process. It is divided into two categories.

1. Physical ripening;

2. biochemical ripening The following criteria are influenced by the cream ripening:

• Consistency, firmness, and spreadability of butter.

• Basic water content of butter during the manufacturing process (bound water in butter, which cannot be removed by any mechanical treatment).

• Buttermilk fat content, which has to be minimized.

The melting and solidification behavior of fat depends on the attached fatty acid, which indicate the hardness of the butterfat.

Natural hardness is caused mainly by seasonal feeding of the milk animals. Winter feed with a great deal of dry feed or roughage yields a hard butterfat with a high percentage of saturated and short-chain fatty acids and few double bonds in the fat molecules.

Summer feeding (green grass) results in fat with longer chains and a higher percentage of unsaturated fatty acids with many double bonds. We therefore distinguish between summer fat and winter fat or summer cream and winter cream.

The process of making dried milk involves eliminating water from milk, primarily through spray or roller drying. It is regarded as a significant sector of the dairy industry and is made from whole cow, buffalo, or standardized milk. Skim milk powder (SMP) is made from milk after the fat has been removed whereas whole milk powder (WMP) is made from whole cow or buffalo milk

FSSA (2006) Standard Of Milk Powder According to FSSA (2006), Milk powder is the product obtained by partial removal of water from the milk of cows and/or buffalo. The fat and/or protein content of the milk may be adjusted by the addition and/or withdrawal of milk constituents in such a way as not to alter the whey protein to casein ratio of the milk. It shall be of uniform color and shall have pleasant taste and flavor, free from off-flavor and rancidity. It shall also be free from vegetable oil/fat, mineral oil, thickening agents, added flavor, and sweetening agents. It may contain food additives. It shall conform to the microbiological requirements prescribed by FSSA (2006).

Water activity, high storage temperatures, longer than usual storage times, high product moisture content, high processing temperatures, and container headspace are some of the variables that affect the Maillard reaction in dried milk.

Casein and whey proteins are the major proteins present in milk. Unlike casein, whey proteins are heat-labile. Whey protein fractions present in milk are α-lactalbumin, β-lactoglobulin, bovine serum albumin, immunoglobulin, euglobulin, and lactoferrin. β-lactoglobulin and κ-casein interact during heat treatment. When milk is refrigerated for longer than 24 h, it forms γ-casein and protease-peptone fractions.

2.1 Introduction
The continuous production of dry milk has become consistently significant within the dairy industry and is expected to continue growing due to its advantageous features. These include improved shelf life, reduced storage
requirements, and lower transportation costs, all of which contribute to favourable economic outcomes.
For example, non-fat dry milk is also known as skim milk powder, dried skim milk, non-fat dry milk solids, or dehydrated skim milk. Similarly, products like dried whole milk, dried cream, and dried buttermilk are often regarded as dried or powdered whole milk, cream, and buttermilk, respectively, based on their specific compositions.
2.2 Types of Dried Powder
1. Nonfat dry milk
2. Dry whole milk
3. Dry buttermilk
4. Dry whey
5. Dry ice cream mix
6. Dry creams (sweet or sour)
7. Dry skim milk vegetable fat products
8. Malted milk Powder
9. Cheese powders (Cheddar, Blue, etc.)
10. Sweetened chocolate flavoured non fat dry milk
11. Coffee creaming products
12. Sodium or Calcium Caseinates
13. Dry high acid milks
14. Partly skim milk powder
15. Infant milk food

The terms “cultured dairy foods,” “cultured dairy products,” and “cultured milk products” are other terms for fermented dairy products. Lactobacillus, Lactococcus, Leuconostoc, and other lactic acid bacteria, along with yeasts in certain products, are used to ferment milk to make these dairy products. The product’s shelf life is extended through fermentation, which also improves the product’s taste and milk’s digestibility. There is a wide variety of fermented milk products available, each with unique flavors and attributes. The following categories apply to fermented milk products, based on the type of fermentation.

Changes in Nutrients Resulting from Fermentation

Fermentation lowers the lactose content in fermented milk products; however, if the starting milk is concentrated or fortified, the finished product’s lactose content may be higher than that of liquid milk.

The composition and content of protein and total amino acids are comparable to those of raw milk. Casein degradation is small compared to cheese, accounting for not more than 1% of the total protein. While some products of casein degradation are used by the starter microorganisms, others build up as free amino acids in the fermented kinds of milk. The amounts of free amino acids that build up differ depending on the species. Generally, proline is increased in large quantities, followed by serine, alanine, valine, leucine, and histidine. As a result of continuous starter culture activity, the level of free amino acids increases during storage. A limited degree of lipolysis occurs during the manufacture of fermented milk. The amount varies depending on the type of species, but the pattern and concentration of free fatty acids are both impacted. During fermentation and the breakdown of amino acids, trace amounts of volatile fatty acids are also produced.

Very little is known about the basic principles governing the chemistry of flavour or fragrance. In English, the term aroma chemicals is used for both fragrance and flavour compounds. Any compound with a sufficiently high vapour pressure will have an odour and this is normally of the molecular weight of around 300, a relatively low polarity granted (Frater et al., 1998). Generally only compounds with pleasant smell are considered to fall under the realm of fragrance chemistry, but purified individual components from a mixture may have a malodour. Almost all ancient civilizations had their tradition of making fragrances from natural materials, mostly of plant origin, but also of animal origin – these are mostly essential oils, exudates, balsam and resins (Arctander, 1969).
 
It was in the latter half of the 19th century that synthetic fragrance chemicals were experimented upon and brought into the market, examples being coumarin (Fig. 1) (in the year 1866), salicylaldehyde (Fig. 2) (1876), vanillin (Fig. 3) (1876), phenylacetaldehyde (Fig. 4) (1883), piperonal (Fig. 5) (1890), musk xylol (Fig. 6) (1891) and b-ionone (Fig. 8) (1893) (Frater et al., 1998).

The Structure of Proteins

Proteins are composed of building blocks called amino acids. A string of amino acids is called a polypeptide chain. Once such a chain has folded into its working three-dimensional shape, it is a protein. Though there are tens of thousands of different proteins, all of them are put together from a starting set of 20 amino acids. It is the order in which the amino acids are linked in a polypeptide chain that determines which protein will be produced.

One of the most consumed and well- known milk products in the Indian subcontinent is ghee. It is a by- product of tradition, prepared both at organized dairy plants and the household level for a well- established market. Ghee is traditionally made from the milk of cows or buffalo. The tetrapyrrole pigments biliverdin and bilirubin are responsible for the distinctive color of buffalo ghee. On the other hand, ghee is golden yellow due to the presence of carotenoids in cow’s milk. Ghee’s composition changes according to the kind and feeding habits of the animal and can differ from place to place and season to season.

In addition to, being a substantial source of fat- soluble vitamins, essential fatty acids, and other growth- promoting components, ghee is a rich source of energy. Its value as food for humans is enormous. Additional attributes related to medicine are present in ghee. Ghee can improve one’s physical and mental attributes and treat eye conditions like ulcers. Ghee is used in religious and ceremonial rites in addition to being consumed.

Composition

Ghee is a complex lipid composed of mixed glyceride which makes up 99–99.5% of its total content. In addition, it has trace amounts of calcium, magnesium, phosphorus, iron, copper, and fat- soluble vitamins, tocopherols, carbonyls, hydrocarbons, carotenoids, free fatty acids, phospholipid, sterols, and sterol esters

4.1 Introduction
Human milk widely acknowledged as the optimal source of nutrition for infants, providing a rich array of components crucial for their growth, repair and development. However, the composition of human milk can vary
significantly within and between feeds, throughout the day, over the course of lactation, and among different mothers and also populations. While this variability is beneficial for infant health and survival, it presents challenges for the management of nutrition of high-risk infants who require precise oversight. The composition of human milk can be altered by factors such as the handling of expressed milk, including how it is stored and pasteurized. Thus, proper management of expressed milk is essential. The recommended practice for infant nutrition is exclusive breastfeeding for the first six months, followed by continued breastfeeding for at least one to two years. Human milk is naturally suited to meet the nutritional needs of infants, providing both nourishment and bioactive compounds that support healthy growth and immunity.
Human milk contains a variety of bioactive components, such as immune cells, anti-infective and anti-inflammatory agents, growth factors, and prebiotics. In contrast to infant formula, which has a fixed nutritional profile, human milk is dynamic and can vary between and within feedings, influenced by maternal factors, environmental conditions, and the methods used for expressing and managing milk.
A thorough understanding of human milk’s composition is vital for effective infant feeding, especially for at-risk infants. It also allows for the assessment of how milk storage and pasteurization may impact its beneficial components. Additionally, some of the bioactive elements in human milk are being studied for their potential use in medical treatments, either as preventive or therapeutic agents.

Commercially, one of the most significant milk products is ice cream. It is a frozen product which is usually made from milk or cream that has been f lavored with fruits like peaches or strawberries, and spices like vanilla or cocoa, or with sugar or a substitute. Stabilizers are sometimes combined with food coloring. Ice cream mix typically contains 10.0% milk fat, 11.0% solids not-fat, 14.0% added sugar, and 0.3% additives like an emulsifier, stabilizer, f lavor, and color substances.

Standard of Ice Cream

According to FSSA (2006), ice cream, kulfi, chocolate ice cream or softy ice cream means the product obtained by freezing pasteurized milk prepared from milk and/or other products derived from milk with the addition of sweetening agents and fruit products, egg products, coffee, cocoa, ginger, and nuts. It may also contain chocolate, and bakery products such as cake or cookies as a separate layer and/or coating. It may be frozen hard or frozen to a soft consistency. It shall be free from artificial sweeteners. It shall have a pleasant taste and smell free from flavor and rancidity. It may contain food additives. It shall conform to the microbiological requirements as given in FSSA (2006).

3.1 Malted Milk
Malted milk, originating from the ideas of British pharmacist James Horlick in the 19th century, was initially marketed under the name “Diastoid” before being trademarked as “malted milk” in 1887. Although initially targeted
for infants and invalids, its appeal expanded due to its nutritional value, convenience, digestibility, and palatability. Recognized globally for its lightweight, non-perishable nature, and high-calorie content, malted milk is
created by evaporating a mixture of malted barley, wheat flour, and whole milk until it forms a powder.
There aremainly two types of malt powder: diastatic and non-diastatic. Diastatic malt containing enzymes breaking down starch into sugar, aiding in dough rise and crust formation, particularly in bread making. Non-diastatic
malt lacks active enzymes and is primarily utilized for flavor enhancement, commonly in beverages. It may also include sugar, coloring agents, and other additives to improve taste and appearance.
3.2 Malting
Malting is a crucial process employed in treating cereal grains, such as barley, by inducing germination through soaking in water followed by halting the process through drying or heating with hot air. This technique encompasses two main stages: sprouting and kiln-drying. The term “malt” encompasses several products of this process:
1. Malted grains: These are grains, like barley, that have undergone the malting process.
2. Malt sugars: These are sugars, predominantly maltose-rich, derived from malted grains, often utilized in baking, such as baker’s malt.
3. Malted milk products: These include beverages like malted milkshakes, made using malted milk.

The native and applied organic matter play an important role in terms of nutrient adsorption , nutrient mobility and microbial habitat on soil. The dominant ions present in soil under a particular agro-ecological situation may or may not be available to the growing plants due to the presence of organic matter. The binding energy and the stability of the organo-metal complexation would play an important role in availability of nutrients to the plants. The organo-metal complexation reaction depends on the nature of the ionic species (ionic/non ionic) present in soil. The organic fractions (Humic acid/Fulvic acid) react with metal ions present in soil to form complexes which may be stable or unstable depending upon the molecular arrangement and degree of coiling of humic/fulvic substances. The surface charge density on clay and soil pH also play an important role to determine the order of stability of different nutrients (macro/micro) in soil.

12.1. Introduction

All soils invariably contain soluble salts. However, physico-chemical and biological soil properties start degrading when excessive amount of salts are accumulated in soil, particularly in rhizosphere, due to several anthropogenic activities and environmental conditions, and crop production is severely affected. Then we refer those soils as salt-affected soil.

The need of intensive agriculture to keep pace with the increasing world population for their food requirement necessitates to bring more agricultural land area under irrigation. However, irrigation system without taking enough drainage provision and poor water quality and its poor management may make the situation worst due to the development of salt-affected soils that ensue unproductive soil and low crop yield. Crops grown on salt-affected soils suffer from high osmotic stress, nutritional disorders due to nutrient (N, Ca, K, P, Fe, Zn) deficiency, specific ion toxicities, poor soil physical conditions and as a consequence, a reduced crop productivity.

Although it is considered that the rocks and minerals on weathering lead to salt accumulation in the soil, but the salt-affected soils are not truly originated from the accumulation of such salts in situ. On the contrary, occurrence of salt-affected soils is due to receiving salts that come from other locations with water. Sea water inundation in coastal belt, irrigation with poor quality water including saline groundwater, poor drainage system, irrigation adopting unscientific ways leading to waterlogging, shallow water table etc. contribute heavily toward development of salt-affected soils. Salt-affected soils may occur under almost all climatic conditions. Their distribution, however, is relatively more extensive in the arid and semi-arid regions compared to the humid regions because of poor precipitation to leach soluble salt adequately. Since evapotranspiration greatly exceeds precipitation in these climatic conditions, the soluble salts move upward with water due to capillary action and are left behind on the surface soil and the rhizosphere, once water is evaporated. The commanding ions of accumulated salts in affected soil are sodium, potassium, magnesium, calcium, chlorides, sulphates, carbonates and bicarbonates. The nature and properties of salt-affected soils are so diverse that they require specific approaches for their reclamation and management. Therefore, it is necessary to know their origin, formation, nature, chemistry and properties in detail to classify them into groups for their proper management to maintain sustainable agriculture.

Silage fermentation is a complex process involving biochemical changes by microbial populations and the ensiling environment. The chemistry and microbiology of silage fermentation are linked, but the microorganisms are the dominant factor in the fermentation process, and they have the main influence on the quality of the end product. Many species of microorganisms are involved in the fermentation process, and their relative importance varies according to the prevailing conditions. As these conditions change during the fermentation process, the microorganism population changes accordingly. Lactic acid bacteria and clostridia are two main categories of microbes responsible for biochemical changes in silage.

13.1. Introduction

Water is chemically benign. However, its interference in free gas exchange in soil becomes detrimental to crop growth when soils are subjected to waterlogging or plants are submerged with water.Waterlogging of soil refers to a soil condition when the soil attains a moisture regime to such an extent that oxygen is not available in the pore space in enough quantity for plant roots to respire adequately. On the contrary, detrimental gases such as carbon dioxide, methane, hydrogen sulphide, ethylene etc. accumulate in the root zone and adversely influence the growth of plants. Thus, anaerobic condition prevails in waterlogged soil causing depletion of oxygen and increase of CO₂ in root zone, which severely affects aerobic micro-organisms while harmful organisms proliferate and restrict the plant growth. Waterlogging leads to nutrient deficiencies or nutrient toxicities, root tip decomposition and eventually, reduced growth or death of the plant. Physical, chemical and biological activities in the soil are also disturbed due to low temperature. However, this is important to note that plants differ among themselves in their demand for oxygen. Even oxygen demand for same plants differs with its growth stage. Therefore, it is well understood that there is no universal level of soil oxygen that can identify waterlogged conditions for all plants. Mostly waterlogging prevails in the land due to non-permeability of the soil material, the presence of an impervious layer in soil horizon, or a high-water table.

If the reader has endeavoured to follow the basic chemistry in the first chapter, he would be in a positions to follow up the various reactions that take place in soils and which hitherto had baffled him. Soils contain particles of various sizes ; some so fine that they would remain suspended in water for a long time; others so coarse that they would be sieved out by even a coarse sieve. Soils contain some salts that can be washed out by leaching with water; they contain some water which can be readily evaporated away by exposing to hot sun or by heating slightly. They also con-tain a little organic matter which can be burnt away or dissolved in alkali. When all the extraneous substances have been completely removed we are left with what we might call soil framework. This framework gives mechanical support to the roots of the plants. Without this framework the plant would not stand up even if it could be supplied with all the food material.

Let us suppose a soil freed from all the extraneous matter by continuous leaching with water or a dilute acid. In the former case the removal of all the extraneous matter is extremely slow, whereas by leaching with dilute acid everything except the soil framework is removed in a short time.

When soils from different localities are subjected to leaching with dilute acid we find that the soil framework in every case, behaves in a similar manner. No matter from what part of the world the soil has been obtained, the properties of its mineral framework only differ in quantity but not in kind.

Being an essential component of the rich Indian past, traditional dairy products and a sophisticated classification of confections have played a significant role in the Indian economy. Depending on how it is processed, it has significant social, cultural, and economic significance. These products have been developed over a long period using a combination of experience, traditional wisdom, and culinary skills. India is emerging as the highest milk- producing country in the world with an annual production of 221.1 million tons in the year 2021–22 (Source: Basic Animal Husbandry Statistics, MoFAHD, DAHD, GoI). An estimated 50% of the milk produced in India is used to make a range of traditional dairy products, including paneer, dahi, ghee, khoa, and shrikhand. The product is not only well- established in the Indian market, but it also has significant export potential due to the large Indian diaspora living all over the world.

All native milk products that have developed over time using locally accessible technologies are referred to as traditional Indian dairy products or Indian indigenous milk products. The Indian masses’ economic, social, religious, and nutritional well- being are greatly influenced by traditional dairy products.

Classification of Traditional Indian Dairy Products

Traditional dairy products in India are typically made, packaged, and/or sold using time- honored methods without the use of machinery or meticulous documentation of the procedure. These products do, however, have several technological advantages, including their widespread appeal, reduced cost of production, straightforward manufacturing process, adoption at the rural level or collection center, large profit margin, and abundance of employment opportunities. These products are categorized according to the manufacturing principle.

Milk is the secretion of the mammary glands of animals. For human consumption, milk is that liquid obtained from the cow or the buffalo during the period following at least 72 hours after calving or until the milk is colostrums-free. It is a complex biological fluid consisting of seven main components: water, fat, protein, sugar (lactose), minerals, vitamins and enzymes. Milk is a white opaque fluid in which fat is present as an emulsion, protein and some mineral matters in colloidal suspension and lactose together with some minerals and soluble proteins in true solution. The opacity of milk is due to its content of suspended particles of fat, proteins and certain minerals. The colour varies from white to yellow depending on the carotene content of the fat. Skimmed milk is more transparent with a slightly bluish tinge. Milk of a good flavour has a pleasant, slightly sweet taste, and no odour. It is an excellent source of calcium, phosphorous and riboflavin. Vitamin A and D are currently added to whole milk, partly skimmed and skimmed milk.

7.1 What is Chemotaxonomy?
The approach of taxonomy in which chemical features of plants are used in developing classifications or in solving taxonomic problems is called chemotaxonomy, chemosystematics, chemical taxonomy, chemical plant taxonomy or plant chemotaxonomy. Some of the basic chemical features or evidentiary characters include alkaloids, flavonoids, carotenoids, polysaccharides, terpenoids, fatty acids, amino acids, aromatic compounds, etc.
The chemical evidences are useful in establishing relationships among taxa is exemplified (Cronquist, 1980) by the (i) Presence of aromatic plants in Juglandales, (ii) Production of betalains and not anthocyanins by the members of caryophyllales, (iii) Presence of highly aromatic compounds in the members of Lamiaceae, (iv) Presence of alkaloids in Solanaceae, and (v) Presence of tanniferous plants in Sapindaceae.
7.2 Purpose of Chemotaxonomy
Chemotaxonomy has been used at all levels of the hierarchy of classification starting from the rank of ‘variety’ up to the rank of ‘division’ in plants. Moreover, chemical evidences have been used in all the groups of the plant kingdom starting from simple organisms, such as fungi and bacteria, up to the most highly advanced and specialized groups of angiosperms. These evidences are used in the classification of plants with two main purposes, (i) To develop such taxonomic characters which may improve the existing systems of plant classification and (ii) To develop the present day knowledge of phylogeny or evolutionary relationships of plants.

Chemotherapy in Parasitology deals with the treatment of disease caused by different parasites by specific drugs; meanwhile particular drug has got the particular action against the particular parasite. Recently chemotherapy is a extensively used and emerging branch for the control of different stages of parasites that is normally not killed by the conventional methods of treatment. Thus, chemotherapy plays an important role in the treatment and control of parasitic infections by avoiding the outcome of the danger of the disease by treatment of the affected animals. They should have the maximum parasitotrophic action and minimum organotrophic action. It is mainly divided into two types: 1) Rational therapy: It is a mode of treatment based on the pharmacological actions of drugs with relation to disease. 2) Supportive therapy: It is a method of treatment other than drugs, e.g. giving high protein diet in the oedematous condition such as bottle jaw in fascioliosis and amphistomiosis. The drugs used for the killing or complete removal of the parasites from the body of the host called antiparasitic drugs.

Chemotherapy is the procedure of treating a sick or infected plant using chemicals to kill the fungus. Chemotherapy has proven successful in very few circumstances. For example, plants have been treated with antibiotics to minimise the severity of “lethal yellowing” of palm trees caused by Phytoplasma and the decline of pears. Likewise, fungicides have been used to elm trees to mitigate the effects of Ophiostoma ulmi and O? neo-ulmi, the causative agents of Dutch elm disease. The chemotherapy drugs must, however, always be given repeatedly. Systemic fungicides like sterol biosynthesis inhibitors (SBIS), which partially penetrate plant tissues, eradicate recent infestations.

Chemotherapeutic fungicides are a class of systemic fungicides that have some plant mobility. They are capable of eliminating diseases even in parts of the plant that were not exposed to the chemicals. Unfortunately, pathogens develop resistance to systemic fungicides because they are site-specific

Q1. The nitrogen atom of amino group in basic structure of sulfonamide is designated as

1. N1
2. N2
3. N3
4. N4

Q2. Trimethoprim produces synergistic action by interfering the synthesis of

1. Dihydrofolic acid from tetrahydrofolic acid
2. Tetrahydrofolic acid from dihydrofolic acid
3. mRNA from DNA
4. tRNA from DNA

Q3. An ophthalmic sulfonamide is

1. Sulfaguinidine
2. Sulfadimidine
3. Sulfadimethoxine
4. Sodium sulfacetamide

Cherimoya is considered as the most esteemed of the fruits of the genus Annona (family Annonaceae). A. cherimola Mill., because of its limited distribution, has acquired few colloquial names, and most are merely local variations in spelling, such as chirimoya, cherimolia, chirimolla, cherimolier, cherimoyer. The cherimoya is believed to be indigenous to the interandean valleys of Ecuador, Colombia and Bolivia. It is cultivated in Australia, Hawai, Brazil, Mexico, India, Sri Lanka, Jamaica, Spain, Costa Rica, Africa and Argentina. In India it is found growing in states of Maharashtra, Tamil Nadu, (Nilgiris and Palani hills), Karnataka (the Nandi hills) and Andhra Pradesh (Telangana region).

It bears fruits with skin which is thin or thick, may be smooth with fingerprint-like markings or covered with conical or rounded protuberances. The sweet, juicy, white flesh is melting, subacid and very fragrant. The fruit is of a primitive form with spirally arranged carpels, resembling a raspberry. Each segment of flesh surrounds a single hard black bean-like seed.

Cultivars: Fingerprinted, Smooth, Tuberculate, Mammilate and Umbonate are the cultivars having different shapes, texture and morphology.

Uses

The flesh of the ripe cherimoya is most commonly eaten out of-hand or scooped with a spoon from the cut open fruit. It really needs no embellishment but some people in Mexico like to add a few drops of lime juice. Occasionally it is added to fruit salads or used for making sherbet or ice cream. Colombians strain out the juice, add a slice of lemon and dilute with ice-water to make a refreshing soft drink. The fruit has been fermented to produce an alcoholic beverage (Morton, 1987). In Jamaica, the dried flowers have been used as flavoring for snuff. All species of Annona can produce seed oil. Essential oils extracted from soursop (pulp) have industrial applications and the oils are also thought to improve the flavour of processed fruit products.

Genus   : Prunus
Species : avium cerasus, mahaleb L.
Family : Rosaceae
Chromosome No. : 2n = 16, 24, 32

Records indicate that cherries were in cultivation ever since the beginning of civilization. Cherries exhibit vast genetic variability as is evident from the different species which vary in their ploidy level. Sweet cherries (Prunus avium L) are diploid while sour cherries (P. cerasus, L.) are tetraploid, and commercially more important than the other species. Duke cherry has resulted from hybridization between sour and sweet cherry with intermediate tree and fruit characters. Successful cherry cultivation revolves around climatic factors, prime being the extent and spread of rainfall, variation in day and night temperature, occurrence of frosts, high heat day largely determine the type of cherry that will grow successfully in a particular areas. Hence cherry improvement around the world has so far been localized to few selected areas where different cherries have been successfully grown.

1. Introduction

Cherry is the common name of several Prunus species that include sweet cherry (P. avium), tart or sour cherry (P. cerasus), Duke cherry (hybrids between P. avium and P. cerasus). Sweet cherries are believed to have originated from the area between the Black and Caspian seas of Asia Minor. Birds probably carried the seed to Europe prior to human civilization. Cultivation was probably started by the Greeks and continued by the Romans. Its distribution and naturalization have proved extensive, for it is now found wild in areas as widely spaced as northern India, the southern plains of Europe and even on isolated islands such as Madeira. Climatic conditions are the most important limitations on cherry production. Being a deciduous tree, it needs a period of dormancy, which is initiated in temperate regions mainly by a fall in average temperatures in late autumn (Mir et al., 2017). Sweet cherry is grown almost everywhere in the temperate zone. It is a composite genus. Due to its origin, this genus needs warm and light conditions, but can also endure cold winter weather. It requires 550-600 mm precipitation annually. Sweet cherry prefers medium light (pH= 5.5–7.5), deep-layered soil, which is rich in nutrients. The root system of sweet cherry requires aeration and cannot tolerate slack water (Simon, 2004). Many areas of the world, although environmentally suited to cherry production, are currently unsuited to profitable cherry production due to high perishable nature of the fruit.

Prunus avium means “Bird Cherry” in the Latin language, is commonly known as ‘Sweet cherry’. Cherries have pleased the palates of food lovers for centuries. Their ruby-red colour and tangy taste won the hearts of kings, queens and noblemen in the history, making a special place for cherries on their tables. The ultimate celebration of cherries is the National Cherry Festival. It is held every year in July in the “Cherry Capital of the World”-Traverse City, Michigan. This festival originated from a spring ceremony known as the “Blessing of the Blossoms.” Thousands of visitors come from all over the world to celebrate the harvest and of course, eat cherries. A delicious fruit, cherry is rich in protein and sugars. Cherry is an excellent source of minerals like potassium, manganese, magnesium, iron, phosphorous and copper. Good amounts of vitamins (A, B, C and K) are found in cherries. They also contain anthocyanins, melatonin and fibers. It has more calorific value than apple. 

There are many cherry species, but only a few have been domesticated. The sweet cherry trees are large (30–40 feet tall) and usually pyramid shaped. Branches grow upright. The fruits are large, have a deep stem cavity, vary in colour from light yellow to dark red to purplish black. Flowers arise from clusters of 2 to 5 flowers on short spurs with multiple buds at tips; the distal bud develops into a leafy shoot. The flesh ranges in texture from tender to firm, and is sweet. Most sweet cherries are consumed as fresh fruit. The tart cherry, is sometime called “red cherry” or “sour cherry” and may have arisen from an unreduced pollen grain of Prunus avium crossed with Prunus fruiticosa. Trees are very cold hardy, but are shorter lived than sweet cherry. The fruit is relatively small, and have higher acid and lower sugar content than sweet cherry. Tart cherries are used for processing, jam, and pie filling. The Duke cherry is a hybrid of Prunus avium and Prunus cerasus and all gradations between the two species exist, but most varieties more closely resemble sweet cherry. Sweet cherries are the variety most often found in markets. They have a thick, rich, and almost plumb-like texture. Sour cherries are not usually eaten raw, but are widely used for making preserves, candy etc. Sour cherries are much smaller than sweet cherries and all varieties are self-fertile. Cherries are cultivated all over the world and the top 3 producers of cherry are Turkey, USA and Iran. The cultivated forms are of the species sweet cherry (Prunus avium) to which most cherry cultivars belong, and the another sour cherry (P. cerasus), which is used mainly for making preserve etc. Both species originate in Europe and western Asia; they do not cross pollinate. Some other species, although having edible fruit, are not grown extensively for consumption, except in northern regions where the two main species will not grow.

• Native to temperate regions of Northern Hemisphere.
• Chilling requirement – 2000-2700 hr, highest among temperate fruits.
• Heavy rainfall during flowering causes – Blossom wilt.
• Heavy rainfall during ripening causes fruit cracking.
• In Europe, a wine – ‘Kirschwasser’ is distilled from the pulp of cherries.
• Most of the commercial varieties of cherry are self-sterile.
• Seedling rootstock – Pazza, Mahaleb, Mazzard
• Clonal rootstock – Colt, Mazzard, F-12/1
• Cherry fruits are the first to appear in the market among temperate fruits.
• Cherry has more calorific value them apple.
• Donar vars: Stella, Vista, Vic, Seneca, Vega.

7.1 Introduction

Cherry is one of the important temperate stone fruits of the world. It is widely grown in the cooler climates where the span of winter is wide and very much pronounced. Sweet cherry is tall, attaining a height of 18 m, and pyramidal form. The branches are usually erect, and leaves are large, thin, variable pubescent beneath and coarsely serrated. Sweet (Prunus avium L.) and sour (P. cerasus L.) cherry ripen first among stone fruits followed by apricot, peach and plum. Sweet cherry comes first on the fresh market; hence, it is in high demand during late spring and early summer. Sweet cherry cultivars with red fruit colour lead the market while cultivars of yellow, white, or blush colour are in less demand. Sour cherries have smaller fruit size and are less firm than sweet cherries. The vast majority of the sour cherries are processed. The tree of sour cherry is usually 6-9 m tall, open headed, round topped or spreading and often without a central leader. The leaves are much smaller, dark green in colour and more numerous and trees are hardier than those of sweet cherry. Diameter of sour cherry fruit is about 2 cm.