eChapter Name: Ion Exchange Reactions and Chemical Equilibria in Soil
9789391383602
eBook Name: SOIL CHEMISTRY AND PLANT NUTRIENTS
by Premasis Sukul
8.1. What is an ion exchange reaction and its application in soil system
Ion exchange is a reversible chemical reaction between two substances, either between two electrolytes or between an electrolyte solution and a solid complex as well as between two solid phases (if in close contact with each other), where ions of equal charge may be interchanged in equivalent proportion.
Organic colloids and inorganic micelles (clays) are sites of ion exchange. Soil contains silicate clay minerals which exhibit charges due to isomorphous substitution as well as due to the pH dependant charges for ionisation of hydrogen and hydroxide functional groups. Organic matter present in soil also contributes to the pH dependent charges due to the presence of various active functional groups. Thus, the organic and inorganic colloids present in soil bear positive or negative charges. Electric charge on soil particles is neutralized by equivalent amount of oppositely charged exchangeable counter ions, held by coulomb forces and van der Waals forces. Ca+2, Mg+2, H+, K+, Na+, NH4 +, Al+3, Fe+3, Fe+2, Mn+2, etc. are the common cations present in soil where Ca+2 serves as the dominant ion. However, Na+ and Al(OH)2 + are the dominant cations found in the exchangeable phase in strong alkali and strong acid soils, respectively. SO4 - 2, Cl-, HCO3 -1, NO3 - etc. are the most common anions found in soil to neutralize positively charged soil colloids.