eChapter Name: Recent Advances of CuFe2O4 as a Supporting Catalyst in Organic Chemistry
9789372193862
eBook Name: FRONTIERS IN ORGANIC CHEMISTRY RESEARCH AND ADVANCES
Introduction
Over the past few decades, magnetic nanoparticles (MNPs) have been showing great importance in the field of organic synthetic reactions, catalysis, sensors, biomedicines, environment rehabilitation, etc. (Gawande, M. B. et al., 2013; Del Rio, M. et al., 2022). Numerous research teams have recognized the significance of solid support materials for the creation of environmentally acceptable nano catalysts with high catalytic activity in light of the infinite advantages of MNPs (Sharma, R. K. et al., 2016; Gawande, M. B. et al., 2013; Deng, J. et al., 2011; Nasrollahzadeh, M. et al., 2015; Hudson, R. et al., 2014; Payra, S. et al., 2017; Chng, L. L. et al., 2013; Parandhaman, T. et al., 2017; Zhang, F. et al., 2014; Pourjavadi, A. et al., 2012). Heterogeneous catalysts in organic chemistry are solid catalysts that, while remaining in a distinct phase (usually solid) from the reactants (generally liquids or gasses), promote chemical reactions without being consumed in the process. These catalysts, which have multiple benefits such as ease of separation, recyclability, and selective reactivity, are essential in a variety of industrial processes and laboratory reactions (Lattuada, M. et al., 2007; Jiang, K. et al., 2011). The standard formula for ferrite nanoparticles is MFe2O4, where M is usually divalent metal ion like copper (Cu), zinc (Zn), or nickel (Ni), and iron (Fe) is the common metal (Kazemi, M. et al., 2018). These nanoparticles work very well as heterogeneous catalysts in a variety of chemical reactions because of their special magnetic and electrical characteristics.Because of its special qualities as a catalyst in a variety of processes, copper ferrite (CuFeO4), a mixed-metal oxide, has drawn interest in organic chemistry (Kharisov, B. I. et al., 2019; Zhu, J. et al., 2014; Vannucci, A. K. et al., 2012). It is a spinel-type ferrite that can catalyse a variety of organic transformations because it combines iron and copper in a stable, highly active structure. With benefits including high stability, reusability, and low toxicity, these catalysts are frequently employed in processes like oxidation, coupling, and reduction (Taghavi Fardood, S. et al., 2018). The Figure 1 represents schematic diagram of a reaction where the ferrite nanoparticles as catalyst have been recovered with the aid of an external magnet after the formation of reaction product.